Двигательная установка. C5.142. [Редактировать]


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Дата загрузки: 2017-12-26
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0.14/5
... L.. Yucca filamentosa L. Yucca gloriosa L. 1110/C5-C6 1110 / C3-C4 Aitoniaceae... 8400 1108 / C2 1108 / C3-C5 Aloaceae Aloe arachnoides Thunb.. Aloe...-B8; C1-C3 955 / C4-C5 955 / C7-C8 Amaryllidaceae Amaryllis... 27/ C4 27/ C3 27/C5 27 / C6-C7 Anthericaceae Anthericum... / C2-C3 1140/C4 1140 / C5-C6 Species name Catalogue number... 1000 / C1-C3 1000 / C4-C5 1000 / C6-C7 Araliaceae Aralia... 765 / 138; C1 765 / C2-C5 6101 6109 6110 Cynoglossum scorpioides... 5417 679 / B6-B7 667 / C5-C8 Butomaceae Butomus umbellatus L.. Buxaceae...-C7; 678 / Al-A5 677/C5 Campanula sibirica Pall., var.. iberica... sempervirens L.. 3701 449 / C4 449 / C5-C8; Lonicera tatarica... Lonicera xylosteum...-B8;C1-C2 131 / C3-C5 Species name Catalogue number Fiche... holostea L.. 998 C1-C4 127 / C5-C8; Stellaria latifolia Pers.. Stellaria... Fiche number 8028 8030 1057 / C5-C7 1057 / C8; Casuarinaceae Casuarina...; C1 203 / A5 202 / C3-C5 202 / C7-C8 Ceratophyllaceae 8087...; C 1-C2 960 / C3-C4 960 / C5-C8 Species name Catalogue number... 8601 1135/ C2 1135/C3-C5 Tradescantia discolor I'Herit,. Tradescantia divaricata.... Anthemis artemisiaefolia Willd. 5173 642 / C5-C6 547 / B8; C1-C3... / B8; C1-C3 607 / C4-C5 Species name Catalogue number Fiche... / B7-B8; C1-C4 630 / C5-C8; Crepis d ioscorid is L.. Crepis...; B1-B8; C1 517 / C2-C5 Species name Catalogue number Fiche... / C2 584 / C3 584 / C4-C5 Pallasia grandiflora Ait.. Parthenium hysterophorus... 486 / C3-C4 486 / C5-C7 530 / C5 530 / C6-C7 527... 354 / C1-C2 354 / C3-C5 359 / C5-C8; 360 / Al -A2...-B8 360 / C2 360 / C3-C5 360 / C6-C8; Sempervivum tectorum... L.. 523 524 525 65 / C4-C5 Iberis cepeaefolia Wulf, Iberis ciliata... / B4-B8 / C1-C2 / C3-C5 Species name Catalogue number Fiche... Schkuhr. 1105 1106 1108 142 / B5-B7 142 / B8; C1-C3 8085... 5444 5445 5446 682 / 131 142 C4 Empetraceae Empetrum album L.. Empetrum... number Euphorbia piiosa L. 7838 1031 / C5-C7; Euphorbia piiuiifera L. 7839 1032...-B7 1033 / 138; C 1 1033 / C2-C5 1033 / C6-C7; 1034 / Al... -A4 1040 / C6-C7 1045/C5 1042 / C5-C6 1042 / C7-C8... / B8; C1-C2 749 / C3-C5 749 / C7-C8; Erythraea centaurium.../C1 189 / C2-C4 189 / C5-C8; 190 Al Pelargonium scandens... calaba L.. 1109 1110 1146 81 142 C5 142 / C6-C8 147 / A5-A7... 8549 1127 / C3-C4 1127 / C5-C6 Ornithogalum sp.. Ornithogalum trigonophyllum... -A2 763 / C2-C4 763 / C5 764 / A4 Hydrocharis morsus-ranae... / B4-B8; C1-C4 1102 / C5 8347 8348 Gladiolus laccatus Jacq...; C1-C2 Krameriaceae 742 88 / C5 Ajuga alpina L. Ajuga arenaria L. Ajuga... 903 / B7-B8 865 / C3-C5 919 / C5-C8; 920 / Al -A6... 864 / C1-C4 864 / C5-C7 879 / C5 880 / A3 879 / C6... Salvia nilotica Jacq. 91 863/C5 7171 6911 Salvia bullata Schusb... Teucrium campanulatum L.. 7181 912/Cl-C5 912 / C6-C8 913 / Al... number Fiche number 1738 208 / C5 2478 2588 2589 2590 295... occidentalis L. 217/C3 217 / C4-C5 302 / B8 302 / C1-C2..... Ceratonia siliqua L.. 304/A6 / C4-C5 / C6-C8 / Al / A2 / A3... / C2 274 / C3-C4 274 / C5-C7 Species name Hedysarum candidum... anil L.. 275 / C2-C4 275 / C5-C8 2331 2341 Hedysarum pictum...-A8 163/81 147 / C3-C5 Species name Catalogue number Fiche... -A2 1134 / A3-A8 1132 / C5 Melastomataceae 3134 3136 3138 116... 6046 760 / Cl-C4 760 / C5-C8 Moraceae Artocarpus integrifolia L. Broussonetia... / C8; 732 / Al -A2 731 / C5-C6 Myrtaceae 3061 Baeckea densifolia... 940 / C1-C3 940 / C4-C5 940 / C6-C8 Naucleaceae Cephalanthus...; B1-B3 737 / C2 736 / C5 Nyssaceae Nyssa biflora Mch. Nyssa... ensifolia Sw.. 8242 8243 1087 / C5-C7 1087 / C8 1073 / A6...; 27 / Al -A2 Palmae 1136 C5 Pandanaceae Pandanus utilis Bory.. Papaveraceae... L.. Chelidonium majus L.. 124 30 / C4-C5 31 /Al-A4 31 / A5...; C1 1003 / C2 1003 / C3-C5 Species name Catalogue number Fiche... / C2 936 / C3 936 / C4-C5 Species name Catalogue number Fiche... p enaea L . Polygala sanguinea L. 129 86/ C5 86 / C6-C7 86/ C8... / I C5-C6 / 1 /C1-C4 1 1 1 L.. 140 139 161 9 8 7 1 1 135 44 143 142 139... 3 2 127 129 C2-C3 / 18 C5-C7 / 18 1 All. halleri Pulsatilla... L. Agrimonia odorata Ait, 2761 328 / C5-C6 328 / C7 328 / A5...-B5 319 / B6-B8; C1-C5 Species name Catalogue number Fiche... / B6-B8; Cl 326 / C2-C5 317 / B2-B3 Anthospermum aethiopicum... 466 / C5-C8; Asperula crassifolia L. 3830 Rubiaceae 467 Al 142 467 / A2... / B7 1065 / B8; C 1-C4 1065 / C5-C6 1065 / C7 1066 / Al... L. Thesium Iinophyllum L. 7771 1018/C3-C5 1018/C6 1019/A1-A8... 214 / A6-A8 7619 1001 / C5-C7 Chrysosplenium alternifolium L. Chrysosplenium oppositifolium... / B4 / B5-B7 798 / C2-C5 Species name Catalogue number Fiche... 1138 / B5-B8 1138/Cl-C5 Staphyleaceae 1776 1777 1778 1354... L. Symplocaceae Symplocos tinctoria L'Herit. Tamaricaceae 142 / B3 Reaumuria hyperioides Willd.. Reaumuria... 1101 142 B4 141 / C2-C3 141 / C4-C5 141 / C6-C8; 142 / Al-A3 Tamarix germanica L. Tamarix tetrandra Pall. 1102 1103 142 / A4-A7 142 / A8; B1-B2 8107... L. Turnera racemosa L.. Turnera ulmifolia.... 383/C5 383 / C6-C7 Typhaceae Ulmaceae... sativa Duroi 7947 7951 1047 / C5 1047 / C6-C8; 1048 / Al... L. Chaerophyllum hirsutum L. 3471 3472 438 / C5-C7; 439 / Al -A5 439... Jacq.. 162 396/C4 396/C5 Species name Catalogue number Fiche...



Дата загрузки: 2017-09-24
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0.15/5
... ............................................................................................. 140 5.7.1 - Synthesis general................................................................................................ 140 5.8 - Acknowledgments ................................................................................................... 142 5.9 - References ............................................................................................................... 143 Page Chapter 6: Synthesis... of Royal Society London A, 1852, 142, 463-562. [2] Czarnik, A.W.; Accounts of... (C4), 127.87 (C3 and C5), 148.35 (C2), 148.70... (C4), 127.41 (2 — (C3 and C5), 127.56 (2— C4’), 128.62... C6’), 129.04 (2— (C3’ and C5’)), 147.79 (C2), 148.91....09 (2×C3’and 2×C5’), 127.57 (C3 and C5), 127.96 (2×C4... (CH3), 52.94 (αC), 119.36 (C5), 125.46 (C1), 126.15... (αC), 80.27 (C(CH3)3), 120.09 (C5), 125.25 (C2), 128.62... (αC), 80.11 (C(CH3)3), 115.30 (C5), 117.33 (C2), 119.89...)3), 114.99 (C2), 116.54 (C5), 127.56 (C1), 127.99...’ or C5’), 132.59 (C3’ or C5’), 134.98 (C3), 142.73 (C2...), 115.71 (C6’), 116.33 (C5), 127.71 (C1), 129.76...), 135.12 (C3), 135.79 (C5’), 144.76 (C4’), 149.79....97 (C3’), 130.31 (C5’), 132.79 (C5), 142.28 (C3a), 149.59....73 (C3’), 130.84 (C5’), 133.24 (C5), 141.26 (C3a), 149....97 (C3’), 130.31 (C5’), 133.85 (C5), 142.33 (C3a), 149.49... (β CH2), 53.01 (αC), 109.92 (C5’), 119.40 (C7), 126.57...), 131.38 (C3’), 132.34 (C5), 141.36 (C3a), 151.70....90 (C2), 133.34 (C5), 135.93 (C5’), 141.18 (C3a), 145....06 (C4), 132.55 (C5), 135.41 (C5’), 141.34 (C3a), 145... .............................................................................................. 140 5.7.1 - Synthesis general ............................................................................................... 140 5.8 - Acknowledgments ................................................................................................... 142 5.9 - References ............................................................................................................... 143 129 Chapter 5 5.1 - Graphical...’), 125.18 (C3’’), 126.02 (C5’’), 127.61 (C1), 128.21 (C4’’), 129.49 (C5), 133.51 (C4’), 134.95... (C2’ or C2’’), 141.09 (C5’), 142.88 (C2’ or C2’’), 149...), 124.43 (C4’), 125.07 (C5’’), 125.90 (C3’’), 126.31... (C3’), 132.85 (C5), 136.19 (C2’’), 142.30 (C5’), 142.35 (C3a), 149...), 124.47 (C4’), 125.13 (C5’’), 125.79 (C3’’), 126.58... (C3’), 133.01 (C5), 136.10 (C2’’), 142.20 (C5’), 142.03 (C3a), 149...), 124.41 (C4’), 125.24 (C5’’), 125.80 (C3’’), 126.57....41 (C5), 136.35 (C2’’), 141.03 (C3a), 142.33 (C5’), 151.62... for derivatives 4a-c and 6a-c. 142 13 C NMR, MS and HRMS... (C2), 128.97 (C3’’ and C5’’), 130.51 (C3’), 131.22 (C5’), 133.08 (C5), 138.12 (C1’’), 141... (C6), 128.37 (C3’’ and C5’’), 128.62 (C4’), 128.91....40 (C3’), 131.83 (C5’), 135.22 (C5), 138.24 (C1’’), 141... C6’’), 128.97 (C3’’ and C5’’), 137.84 (C1’’), 155.28... C6’’), 128.85 (C3’’ and C5’’), 137.64 (C1’’), 155.67... (0.14 g, 42 %), melting point = 140-142 ºC, C33H38N4O7S2, FW= 666.8. Elemental Analysis....80 (C3’), 131.01 (C5’), 133.10 (C5), 137.91 (C1’’), 141...), 120.5 (C4 BOT), 123.03 (C5 Trp), 123.62 (C3’ ZNO2....77 (C 4’’), 128.27 (C3’’ and C5’’), 128.56 (C4’), 128.64....31 (C3’), 131.76 (C5’), 134.77 (C5 BOT), 135.13 (C7a... (C1’’), 141.28 (C3a BOT), 142.97 (C1’ ZNO2), 147.23...), 125.21 (C4’), 125.89 (C5’’), 125.96 (C3’’), 126.18...’’), 128.67 (C3’), 131.68 (C5), 135.00 (C2’’), 141.63 (C5’), 141.69 (C3a), 149.26 (...), 125.47 (C4’), 125.10 (C5’’), 125.93 (C3’’), 126.38... (C4’’),128.56 (C3’’’ and C5’’’), 128.89 (C2’’’ and C6....25 (C5), 136.24 (C2’’), 137.60 (C1’’’), 142.33 (C5’), 142.47 (C3a... (C6), 127.36 (C5’’), 128.28 (C3’’’ and C5’’’), 128.75 (C4...’’’), 131.48 (C3’), 134.16 (C5), 135.15 (C2’’), 138.35 (C1’’’), 141.50 (C5’), 141.54 (C3a), 148.89...



Дата загрузки: 2017-09-25
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0.19/5
... lediglich in ihren Substituenten am C5 des Pyrrolidin-2,4-dionsystems (H oder Methyl... 141 tButylpropionat Propyl Heptyl 26 142 Propansäure Ethyl Pentadecyl 23... N C6H13 O 122 O OH N C14H29 O O OH 142 57 Spezieller Teil a Angegebenen sind...-Probe) wurde somit die Substanz 142 (Tabelle 4-4) ausgewählt. Überraschenderweise erwies... H 29 N O O a) HO N O OH C 14H 29 O 142 147 O HN H NH H b) O S N H O HN H H H S O O O NH... per Western-Blot erreicht werden.[142] Des Weiteren sollte die Bindung....8 (C4), 101.8 13 (C3), 57.9 (C5), 33.0 (C1’), 32.1 (C7), 29....7 (C4), 101.8 13 (C3), 57.9 (C5), 32.8 (C1’), 32.1 (C7), 29....8 (C4), 101.8 13 (C3), 57.9 (C5), 33.1 (C1’), 32.1 (C7), 30....8 (C4), 101.8 13 (C3), 57.9 (C5), 33.0 (C1’), 32.1 (C7), 29....8 (C4), 101.8 13 (C3), 57.9 (C5), 32.8 (C1’), 32.1 (C7), 29....5 (C4), 101.6 13 (C3), 57.6 (C5), 32.6 (C7), 31.8- 29.1 (C8....2 (C4), 102.2 13 (C3), 57.6 (C5), 28.3 (C1’), 19.4 (C7). MALDI....2 (C4), 100.3 13 (C3), 57.9 (C5), 31.2 (C 1’), 28.6 (C7), 18.9 (2CH3...), 116.2 (C10), 102.1 (C3), 57.9 (C5), 32.1 (C1’), 29.8 (C7), 28....), 126.6 (ar.), 102.1 (C3), 57.9 (C5), 34.5 (benz.), 31.9 (benz.), 28....), 114.6 (ar.), 102.6 (C3), 55.5 (C5), 55.1 (OCH3), 45.0 (benz.), 19....), 102.8 (C3), 98.8 (ar.), 56.0 (C5), 55.6 (OCH3), 55.6 (OCH3), 40....0 (CH2=CH2), 101.8 (C3), 57.9 (C5), 32.8 (C1’), 32.0 (C7), 29....), 55.9 (OCH3), 55.6 (OCH3), 55.6 (C5), 40.2 (benzyl.), 33.0 (C1’), 32....1 (C4), 100.7 13 (C3), 62.9 (C5), 32.8 (C1’’), 32.1 (C7), 29....8 (C4), 102.3 13 (C3), 70.4 (C5), 35.8 (C1’’), 32.7 (CHCH2CH3), 32...), 130.0 (C12), 101.8 (C3), 57.9 (C5), 32.8 (C1’’), 32.0 (C7), 29....9 (C4), 102.1 13 (C3), 71.6 (C5), 32.7 (C1’’), 32.1 (C7), 29...)3), 101.5 (C3), 81.0 (C(CH3)3), 62.9 (C5), 34.4 (C1’’), 33.0 (C7, C2...), 101.5 (C3), 81.0 (C(CH3)3), 62.9 (C5), 34.4 (C1’’), 32.7 (C7, C2....), 101.6 (C3), 81.0 (C(CH3)3), 63.0 (C5), 41.5 (C1’’), 32.9 (C7, C2....), 123.5 (ar.), 101.3 (C3), 62.6 (C5), 41.7 (C1’’), 33.0 (C7, C2...), 101.4 (C3), 81.0 (C(CH3)3), 63.2 (C5), 41.1 (C1’’), 33.0 (C7), 32...), 101.4 (C3), 81.0 (C(CH3)3), 63.2 (C5), 41.1 (C1’’), 34.0 (C7), 31....5 13 (CH2COOH), 101.4 (C3), 62.6 (C5), 34.4 (C1’’), 32.8 (C7, C2....1 (C4), 171.8 13 (COOtbutyl), 136.7 (C5’’), 135.0 (C2’’), 128.6 (C3’’), 123...’’), 101.3 (C3), 80.7(C(CH3)3), 62.9 (C5), 41.1 (C1’’), 32.7 (C6’’), 32....5 (C4), 173.4 13 (COOH), 137.1 (C5’’), 135.5 (C2’’), 128.8 (C3’’), 123.1 (C4’’), 101.4 (C3), 62.9 (C5), 41.5 (C1’’), 33.0 (C6’’), 32...), 100.8 (C3), 80.3 (C(CH3)3), 62.2 (C5), 33.7 (C1’’), 32.3 (C7), 31..., CHCl3) (S,Z)-3-(1-Hydroxyhexadecyliden)-5-propanoat-1-ethylpyrrolidin-2,4-dion (142) (S,Z)-3-(1-Hydroxyhexadecyliden)-5-tert-butyl-3-propanoat-1-ethylpyrrolidin....5 13 (COOH), 101.4 (C3), 62.6 (C5), 34.5 (C1’’), 33.1 (C7, C2... 98.7 (ar.), 80.9 (C(CH3)3), 63.7 (C5), 55.6 (OCH3), 55.6 (OCH3), 38....), 101.5 (C3), 79.1 (ar.), 68.2 (C5), 35.1 (C1’’), 33.1 (benz.), 32....), 100.0 (C3), 79.0 (C(CH3)3.), 64.9 (C5), 44.0 (benz.), 41.2 (CH), 35....), 100.0 (C3), 78.7 (C(CH3)3), 64.8 (C5), 43.9 (benz.), 41.0 (CH), 37....), 101.4 (C3), 78.7 (C(CH3)3), 64.9 (C5), 43.9 (benz.), 35.3 (benz.), 32....), 127.2 (ar.), 101.6 (C3), 64.8 (C5), 35.7 (C1’’), 34.8 (benz.), 32....), 110.0 (ar.), 100.2 (C3), 64.7 (C5), 41.0 (C1’’), 35.8 (C1’), 34....), 104.8 (C3), 98.7 (C(CH3)3) 64.2 (C5), 55.6 (OCH3), 55.6 (OCH3), 40...), 100.1 (C3), 81.0 (C(CH3)3), 62.9 (C5), 41.2 (CH und C3’), 34....), 100.8 (C3), 77.4 (C(CH3)3), 63.9 (C5), 43.7 (C3’), 41.6 (benz.), 33....4266 [α]20 = -27.0° (c = 0.26, CHCl3) 142 Experimenteller Teil (S,Z)-3-(1-Hydroxyhexadecyliden)-5-(tert-butoxymethyl....7 (CH ar.), 73.4 (C(CH3)3), 65.6 (C5), 59.5 (CH2Ot-butyl), 55.6 (OCH3....8 13 (C3), 73.6 (C(CH3)3), 65.7 (C5), 61.3 (CH2Ot-butyl), 35.4 (C1...), 98.5 (ar.), 73.4 (C(CH3)3), 65.4 (C5), 59.2 (CH2Otbutyl), 55.4 (OCH3), 55...), 99.8 (C3), 45.6 (C1’), 42.9 (C5), 37.9 (C6), 23.7 (CH3). LC....), 98.8 (C3), 55.6 (OCH3), 45.1 (C5), 43.1 (benz.), 38.1 (C6), 37....), 102.1(C3), 79.6 (C(CH3)3), 63.9 (C5), 43.6 (benz.), 40.3 (C3’), 28....), 114.1(ar.), 110.0 (C3), 63.0 (C5), 43.8 (benz.), 40.0 (C3’), 24....2 (C3), 59.3 (benzyl. C10), 55.8 (C5), 48.1(CH2 8), 44.2 (benzyl. C1....6 (C3), 138.4 (C4), 13 133.8 (C5), 131.7 (C6), 126.2 (7), 125.4 (C2...) = 196.1 (C1), 167.4 (C3), 149.7 (C5), 142.9 13 (C6), 137.9 (8), 137.1 (C9...), 168.3 (CH3OC(O)CH2), 13 150.8 (C5), 143.0 (C6), 139.8 (C8), 134...), 172.7 (C4), 150.5 13 (C8), 142.7 (C9), 139.6 (C11), 134.6 (C12....8 (C7), 103.4 (C3), 46.3 (C5), 41.7 (C5 Ketoform), 18.8 (C15), 12.6 (C9...) = 195.8 (C1), 166.6 (C3), 145.2 (C5), 139.7 13 (C6), 139.3 (C8...), 142.8 (CH), 130.1 (CH), 128.8 (CH), 120.1 (CH), 100.3 (C3), 57.4 (C5...) = 193.0 (C1), 164.3 (C3), 143.2 (C5), 143.0- 13 124.6 (CH Keto...), 120.6 (CH), 100.7 (C3), 57.8 (C5), 28.7 (NCH3), 19.0 (C13). LC...) = 196.1 (C1), 166.9 (C3), 145.2 (C5), 143.6- 13 124.3 (CH Keto...), 120.7 (CH), 100.7 (C3), 57.8 (C5), 28.7 (NCH3), 18.8 (C15). LC....4 (C3), 80.7-69.7 (OCH2CH2O), 61.9 (C5), 60.5 (NHCHCH2S), 51.6 (NHCHCHS), 52....2 (C3), 70.3-69.8 (OCH2CH2O), 62.8 (C5), 62.1 (NHCHCH2S), 60.6 (NHCHCHS), 55... Biology 2008, 10, 971-978. [142] O. George, B. K. Bryant, R. Chinnasamy, et al...



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0.13/5
... COMPLEXES D’AGI, D’AUI ET D’AUIII ................................... 142 1.-PROPRIÉTÉS DE LUMINESCENCE DES PROLIGANDS... de jonction alkyle (C3 et C5) et de la nature et... l’ultraviolet (< 400 nm) et le 142 Chapitre IV : propriétés photophysiques des... 0.1032 0.2099 0.0569 ∆ρmax/min/e Å-3 3.142 and -3.203 1.738 and -2.707...), 121.4 (1C, C3), 69.1 (1C, C5), 57.4 (2C, C4), 27.4 (2C...), 120.5 (1C, C3), 72.6 (1C, C5), 54.1 (1C, C4). MS (FAB... (1C, COMe), 18.42 (1C, C5). MS (ES+): m/z 155.2 [M + H+]+. [α]20D = + 3 (589... (1C, C4), 18.11 (1C, C5). MS (ES+): m/z 127.3 [M + H+]+. [α]20D = + 18...-), 138.1 (2C, CArTsO-), 137.4 (2C, C5), 128.5 (4C, CArTsO-), 125.9 (4C... MHz, DMSO-d6) δ: 138.4 (2C, C5), 125.6 (2C, C4), 123.0 (2C...), 68.6 (2C, C6), 59.7 (2C, C5), 58.5 (1C, C1), 28.1 (4C... (2C, CArTsO-), 136.17 (2C, C5), 128.54 (4C, CArTsO-), 125..., DMSO-d6) δ: 136.19 (2C, C5), 122.67 (2C, C3), 121... (2C, CArTsO-), 137.27 (2C, C5), 128.80 (4C, CAr), 128... (2C, CAr), 137.24 (2C, C5), 128.82 (4C, CAr), 128....9 (4C, CAr TsO ), 124.4 (2C, C5), 122.0 (2C, C4), 68.6 (2C... ), 122.7 (2C, C4), 121.6 (2C, C5), 64.3 (2C, C8), 58.6 (2C...), 125.9 (4C, CArTsO-), 123.7 (2C, C5), 122.4 (2C, C4), 188 Chapitre..., C3), 142.0 (1C, C1), 134.9 (2C, C6), 131.1 (2C, C5), 116.1 (2C...), 136.4 (2C, C6), 124.7 (2C, C5), 119.8 (2C, C4), 114.9 (2C...), 132.3 (2C, C1), 129.7 (2C, C5), 129.5 (2C, C4), 129.0 (2C..., DMSO-d6) δ: 181.3 (pseudod, 2C, C5), 146.3 (1C, CArTsO-), 138.1 (1C..., DMSO-d6) δ: 181.3 (dd, 2C, C5, J107C-Ag = 181.9 Hz and... MHz, DMSO-d6) δ: 181.4 (2C, C5), 124.6 (2C, C4), 120.7 (2C... (75 MHz, CD3CN) δ: 181.9 (2C, C5), 124.1 (2C, C4), 120.3 (2C... NMR (75 MHz, DMSO-d6) δ: 142.2 (2C, CAr),141.4 (2.2C, CArTsO... ), 122.1 (2C, C4), 120.1 (2C, C5), 65.4 (2C, C8), 59.8 (2C....2 (2C, C6),146.3 (3.8C, CArTsO-), 142.5 (2C, CAr), 138.1 (3.8C, CArTsO...-), 126.0 (4C, CAr), 124.7 (2C, C5), 121.5 (2C, C4), 72.9 (2C...), 144.3 (1C, C1), 124.6 (2C, C5), 120.0 (2C, C4), 114.4 (2C... (75 MHz, CD3CN) δ: 183.9 (2C, C5), 142.2 (3.2C, CArTsO-), 140.3 (3.2 C, CArTsO-), 128... (75 MHz, CD3CN) δ: 183.9 (2C, C5), 124.2 (2C, C4), 120.5 (2C...), 62.7 (1C, C1), 61.2 (2C, C5), 27.8 (2C, C7 or 8), 27...), 62.8 (1C, C1), 61.4 (2C, C5), 26.6 (2C, C7 or 8), 26...), 143.4 (1C, C1), 124.5 (2C, C5), 119.2 (2C, C4), 113.8 (2C... (75 MHz, CD3CN) δ: 183.1 (2C, C5), 141.1 (2C, CAr), 128.5 (4C... (63 MHz, CD3CN) δ: 183.1.0 (2C, C5), 121.4 (2C, C3), 119.5 (2C...), 63.8 (1C, C1), 60.2 (2C, C5), 27.3 (2C, C7 or 8), 26... (75 MHz, CD3CN) δ: 150.3 (2C, C5), 126.8 (2C, C4), 122.7 (2C...), 126.1 (2C, C2), 124.6 (2C, C5), 122.6 (2C, C4), 60.1 (2C... MHz, DMSO-d6) δ: 167.3 (1C, C5), 139.4 (1C, C1), 138.6 (1C... MHz, DMSO-d6) δ: 166.3 (1C, C5), 144.6 (1C, CAr), 138.6 (1C... 8 10 O 6 Formaldehyde water solution (36%, 0.142 g, 1.7 mmol) and glyoxal water solution... MHz, DMSO-d6) δ: 171.5 (1C, C5), 139.7 (1C, C1), 136.2 (1C...) δ: 164.1 (2C, C7), 138.7 (2C, C5), 138.2 (2C, CAr), 129.5 (4C...) δ: 165.4 (2C, C7), 139.1 (2C, C5), 138.1 (2C, CAr), 128.8 (4C...), 144.4 (2C, CAr), 138.1 (2C, C5), 128.8 (4C, CAr), 127.3 (2C...) δ: 167.1 (2C, C7), 138.6 (2C, C5), 137.1 (2C, CAr), 129.4 (4C...), 139.2 (2C, CAr), 137.1 (2C, C5), 128.8 (4C, CAr), 127.8 (4C... MHz, DMSO-d6) δ: 184.9 (2C, C5), 165.4 (2C, C7), 139.2 13... (63 MHz, DMSOd6) δ: 184.4 (2C, C5), 166.9 (2C, C7), 139.4 (2C...) δ: 166.6 (2C, C7), 162.1 (2C, C5), 148.4 (2C, CAr), 127.0 (4C...): δ = 169.7 (2C, C7), 162.1 (2C, C5), 142.2 (2C, CAr), 128.0 (4C, CAr...) δ: 166.6 (2C, C7), 161.8 (2C, C5), 148.1 (2C, CAr), 126.9 (4C...) δ: 170.2 (2C, C7), 161.2 (2C, C5), 142.1 (2C, CAr), 128.1 (4C, CAr...) δ: 174.1 (2C, C7), 165.2 (2C, C5), 143.3 (2C, CAr), 127.6 (4C...



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...-2 cells, Plant J., 2004, 40, 131-142. Copyright Wiley-Blackwell. Reproduced with... activity with pnitrophenylbutyrate (C4), valerate (C5) and caproate (C6) as that... divided into two orthogonal parts. 142 In a similar fashion, the structure... the following sections. 5.3.4.1 Brefeldin A Brefeldin A, 142 is a macrocyclic lactone that it....212 In cells treated with 142 protein secretion is inhibited at... the cell.214 O HO O H H HO 142 A. thaliana protoplasts were incubated with 100 μM 142 for 30 mins. Following treatment...), 153.1 (C7), 151.8 (QC), 125.4 (C5), 118.1 (C6), 117.9 (C4), 114...), 153.7 (C7), 152.2 (QC), 125.6 (C5), 118.2 (C6), 118.0 (C4), 114...), 153.2 (C7), 151.9 (QC), 125.3 (C5), 118.1 (C6), 117.7 (C4), 114....5 (C4’), 22.3 (C4-Me), 18.7 (C5’), 13.9 (C6’); m/z (ES+): 274.9 [M+H+]+ 191...), 153.5 (C7), 152.0 (QC), 125.4 (C5), 118.2 (C6), 117.8 (C4), 114...’-Me), 18.8 (C4-Me), 17.0 (C5’), 14.0 (C6’); m/z (ES+): 288.8 [M+H+]+ 192...), 153.2 (C7), 151.9 (QC), 125.4 (C5), 118.1 (C6), 117.7 (C4), 114...’), 32.2 (C3’), 31.3 (C4’), 29.1 (C5’), 18.8 (C4-Me), 18.6 (C4...), 152.7 (C7), 151.9 (QC), 125.6 (C5), 118.2 (C6), 117.9 (C4), 114...), 153.2 (C7), 152.0 (QC), 125.6 (C5), 118.2 (C6), 118.0 (C4), 114...), 153.2 (C7), 152.0 (QC), 125.6 (C5), 118.2 (C6), 118.0 (C4), 114...), 152.8 (C7), 152.2 (QC), 125.8 (C5), 118.3 (C6), 118.0 (C4), 114....7 (C2’), 29.5 (C4-Me), 18.9 (C5’), 9.8 (C6’); m/z (ES+): 312.08416 ([M+Na...), 152.7 (C7), 152.2 (QC), 125.9 (C5), 118.3 (C6), 118.0 (C4), 114....8 (C2’), 29.7 (C4-Me), 18.9 (C5’), 18.4 (C2’-Me), 9.9 (C6’); m/z (ES...), 125.5 (C3), 121.3 (C8), 118.2 (C5), 21.1 (Me); m/z (ES+): 187.1 [M+H]+ 2-naphthyl... 127.8 (C7 and C8), 126.7 (C5), 125.8 (C6), 121.3 (C3), 118...’), 142.1 (QC), 132.5 (C5’), 130.4 (C3’), 126.6 (C4’), 125.5 and 124.7 (C5 and... and C8a), 110.5 (C4 and C5), 81.9 (spiroC), 34.5 (C2’), 29... and C8a), 110.5 (C4 and C5), 81.9 (spiroC), 34.5 (C2’), 32... and C8a), 110.5 (C4 and C5), 81.8 (spiroC), 47.8 (C2’), 31...), 130.5 (C4), 120.5 (C3 and C5), 25.6 (tBu), 18.3 (QC), -4.3 (Me...), 122.6 (C4’), 120.3 (C3 and C5), 89.0 (C2’), 86.6 (C3’), 64... C6), 126.3 (C3’’ and C5’’), 120.7 (C3 and C5), 112.5 (C2’’ and...), 122.8 (ArC), 115.5 (C3 and C5), 89.9 (C2’), 85.6 (C3’), 64... and C6), 122.5 (C3 and C5), 21.3 (Me); m/z (ES+): 180.2 [M+H]+ 4-(1-hydroxy...), 122.7 (ArC), 122.1 (C3 and C5), 88.9 (C2’), 87.2 (C3’), 64....5 (ArC), 125.2 (C3’’ and C5’’), 122.1 (C3 and C5), 121.7 (ArC), 118...), 122.6 (C4’), 114.1 (C3 and C5), 89.0 (C2’), 86.6 (C3’), 64... and C6), 126.3 (C3” and C5”), 122.3 (C4’), 114.6 (C3 and C5), 112.5 (C2” and C6”), 86.8 (...), 127.5 (ArC), 113.9 (C3 and C5), 55.6 (OMe), 48.5 (C3’), 44...), 127.3 (ArC), 114.0 (C3 and C5), 87.8 (C2’), 86.8 (C3’), 55...), 128.6 (ArC), 114.6 (C3 and C5), 55.6 (OMe), 41.5 (C2’), 38...), 130.8 (C1), 116.4 (C3 and C5), 94.2 (CH2), 56.5 (CH3); m/z (ES....6 210 (ArC), 116.4 (C3 and C5), 94.6 (CH2), 89.0 (C3’), 86... and C6), 126.6 (C3” and C5”), 122.4 (C4’), 116.9 (C3 and C5), 112.9 (C2” and C6”), 94.5 (...), 144.3 (QC), 133.2 (QC), 132.0 (C5), 131.3 (ArC), 130.7 (ArC), 124...’), 132.0 (pyC), 131.8 (C3’ and C5’), 130.3 (C2’ and C6’), 121... MHz, CDCl3): 155.5 (C3 and C5), 143.3 (C1 and C7), 141...): 156.8 (C5 and C3), 148.5 (C4’), 142.7 (C7 and C1), 142.1 (C8), 138...’ and C6’), 124.5 (C3’ and C5’), 122.0 (C2 and C6), 14....9 (C2’), 156.5 (C3 and C5), 150.1 (C4’), 142.4 (C1 and C7), 136...’), 121.8 (C2 and C6), 117.0 (C5’), 106.6 (C3’), 56.8 (OMe), 15...), 135.1 (C4), 132.7 (C6), 126.3 (C5), 124.2 (C3), 122.3 (C1), 21... C7Me); δC (126 MHz, CDCl3): 152.6 (C5 and C3), 148.0 (C4’), 145...’ and C6’), 123.9 (C3’ and C5’), 120.4 (C2 and C6), 16... C7Me); δC (126 MHz, CDCl3): 154.9 (C5 and C3), 147.1 (C4’), 143...’ and C6’), 124.2 (C3’ and C5’), 120.6 (C2 and C6), 14... C7Me); δC (126 MHz, CDCl3): 155.1 (C5 and C3), 147.1 (C4’), 143...’ and C6’), 123.9 (C3’ and C5’), 120.4 (C2 and C6), 14... MHz, CDCl3): 154.7 (C3 and C5), 142.5 (C1 and C7), 141.4 (C8... MHz, CDCl3): 155.6 (C3 and C5), 142.1 (C1a and C7a), 141.9 (C1...); 177.0 (CHO), 161.0 (C4’), 159.9 (C5), 151.8 (C2), 127.1 (C2’ and...’), 121.9 (C1’), 114.6 (C3’ and C5’), 106.4 (furan C), 55.5 (OMe); m/z (ES...’), 124.1 (C1’), 123.3 (C5), 114.1 (C3’ and C5’), 96.3 (C6), 92.3 (C3...), 125.9 (C2’ and C6’), 124.6 (C5), 124.4 (C1’), 115.1 (C3’ and C5’), 96.4 (C6), 94.0 (C3), 55.9 (...’), 118.6 (QC), 114.7 (C3’ and C5’), 103.1 (C6), 94.2 (C3), 55..., s, Me); δC (126 MHz, CDCl3): 152.6 (C5 and C3), 148.0 (C4’), 145...’ and C6’), 123.9 (C3’ and C5’), 120.4 (C2 and C6), 16... Kuchitsu K., Plant J., 2004, 40, 131 – 142 109 Alberti S., Parks D. R. and Herzenberg.... Dispos., 1998, 26, 868 – 874 142 Mathijssen R. H. J. and van Schaik R. H. N., Eur... B. and Whiteman M., Br. J. Pharmacol., 2004, 142, 231 – 255 226 Khan N., Wilmot...



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... neutral glycine increases dramatically.141,142 In order to gain information...(1-MeC)(gly-N)]+ (a = NH3, NH2CH3).141,142 Thus, the results show that...)(gly-N)]+ (pKa = 2.8 and 2.5, respectively).141,142 44 3,75 3,70 3,65 δ / ppm..., the fully protected PNA pentamer c5 was assembled following a well-established... building blocks yielded resin-bound c5 (30). It was subsequently reacted... of building block 9 to immobilized c5 (30); a) HATU, DiPEA, b) cap reagent... Nterminal amino group of immobilized c5 proceeded almost quantitatively. An incomplete... coupling reaction of 9 with immobilized c5 (33) tr mass amount / % assignment... n.o. s, 7.32 s, 1.92 d, 3.64 m, 4.55 t, 2.15 T-C5 T-C6 T-CO(4) T-CO(2) 109.8 143... 50 A-C6 A-C2 A-C4 A-C8 A-C5 A-C9 48a 155.6 152.9 150... with A-C8 (1J), A-C4 (3J), A-C5 (3J), and A-C9 (3J). The... (3J), b: A-H2 / A-C6 (3J), c: A-H8 / A-C5 (3J), d: A-H8 / A-C4 (3J), e: T-H6... with A-C8 (1J), A-C4 (3J), A-C5 (3J), whereas A-H2 displays couplings... (3J), b: A-H2 / A-C6 (3J), c: A-H8 / A-C5 (3J), d: A-H8 / A-C4 (3J), e: T-H6... A-C5 T-C5 T-C6 T-CO(4) T-CO(2) 51b 157.7 155.6 148.9 142.6 121.6 110.5 142.9 174.4 158.9 Table 5 (continued) C1´ C2´ C3´ C4´ C5... a 4-hydroxymethylbenzoic acid linker. Assembly of c5 was performed using solutions of... (1/1, v/v), 2.5 ml. The immobilized fully protected c5 (30) was transferred into a syringe...), 144.5 (A-C8), 120.5 (A-C5), 51.1 (A-C9), 109.8 (T-C5), 143.0 (T-C6), 174.0 (T-CO....6 (A-C2), 148.9 (A-C4), 142.6 (A-C8), 121.5 (A-C5), 110.5 (T-C5), 142.9 (T-C6), 174.4 (T-CO(4)), 158...´), 73.6 (C3´), 87.3 (C4´), 63.8 (C5´); 195 Pt NMR (DMF-d7... 43 mit dem Deoxyoligonukleotid 46. 142 Die in Kapitel III beschriebene..., Chim. Acta, 1990, 168, 275. 142 F.J. Pesch, H. Preut, B. Lippert, Inorg, Chim...(PO3H)d(T2CTC2TC)-3´-OH}]+ 30* NH2-c5-gly-HMBA-PS 31 trans-[Pt(NH2CH3)2(CHMT)(NH2CH2CONH-c5-gly)]+ 32* N-[(N2-benzhydryloxycarbonylguanin-9-yl...



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...), 68.2 (C2), 66.1 (C3), 52.9 (C5) and 50.8 (OCH3); νmax (KBr...), 68.2 (C2), 66.1 (C3), 52.9 (C5) and 50.8 (OCH3); νmax (KBr...), 67.8 (C2), 65.9 (C3), 53.1 (C5) and 48.7 (OCH3); νmax (KBr...), 67.8 (C2), 63.9 (C3), 51.9 (C5) and 46.3 (OCH3); νmax (KBr...), 68.6 (C2), 64.4 (C3), 53.1 (C5), 50.2 (OCH3) and 21.9 (CH3... Tetrahedron (C2) 65.2 (C3), 52.4 (C5), 50.6 (OCH3) and 40.6 (CH2...), 123.5 (indole C2'), 122.3 (indole C5'), 120.8 (indole C4'), 118.9 (indole...), 67.5 (C2), 65.9 (C3), 53.1 (C5) and 48.6 (OCH3); νmax (KBr..., 1H, NH); δ (13C): 172.8 (CO), 142.1, 140.9, 137.6, 136.4, 130 (Cq...), 67.6 (C2), 64.1 (C3), 52.1 (C5) and 46.2 (OCH3); νmax (KBr... (s, 3H, CH3); δ (13C): 175.7 (CO), 142.0, 140.8, 136.5, 134.9 (Cq), 129...), 69.0 (C2), 64.9 (C3), 53.4 (C5), 50.4 (OCH3) and 22.3 (CH3... (s, 2H, CH2); δ (13C) 174.6 (CO), 142.1, 140.9, 137.1, 136.5, 135.1 (Cq...), 73.4 (C2), 65.2 (C3), 52.9 (C5) 50.8 (OCH3) and 41.0 (CH2....1 (ArOCH3), 54.0 (CO2CH3) and 52.5 (C5); νmax (KBr): cm-1; m/z (ES+): 423...), 56.1 (ArOCH3), 56.0 (CO2CH3), 52.7 (C5) and 21.4 (CH3); νmax (KBr...), 67.6 (C3), 55.5 (ArOCH3), 53.0 (C5) and 40.7 (OCH3); νmax (KBr...), 64.3 (C3), 56.7 (ArOCH3), 56.3 (C5), 53.2 (OCH3) and 21.9 (CH3...), 150.7 (furan C2'), 143.0 (furan C5') 133.1, 133.0 (Cq), 128.2, 128...), 67.1 (C2), 64.3 (C3), 52.7 (C5) and 48.2 (OCH3); νmax (KBr...), 150.1 (furan C2'), 143.1 (furan C5') 133.8, 133.5 (Cq), 128.9, 128...), 69.9 (C2), 65.8 (C3), 53.5 (C5), 51.5 (OCH3) and 22.5 (CH3...), 74.4 (C2), 66.1 (C3), 53.0 (C5), 52.3 (OCH3) and 40.8 (CH2...), 151.2 (furyl C2'), 143.4 (furyl C5'), 142.0, 140.7, 133.3 (Cq), 129.2 (2 x ArCH...), 67.9 (C2), 65.2 (C3), 53.3 (C5) and 49.3 (OCH3); νmax (NaCl...), 68.5 (C2), 67.8 (C3), 53.3 (C5) and 50.9 (OCH3); δB (1H, 300....2 B B Tetrahedron (C2), 64.9 (C3), 52.6 (C5) and 49.4 (OCH3); νmax (KBr...), 68.8 (C2), 64.4 (C3), 53.4 (C5), 52.3 (OCH3) and 22.2 (CH3...), 73.1 (C2), 64.9 (C3), 53.4 (C5), 53.0 (OCH3) and 40.9 (CH2...), 94.2 (C4), 67.6 (C3) 65.0 (C5), 53.0 (C2) and 49.1 (OCH3...), 67.6 (C2), 67.2 (C3), 53.1, (C5) and 52.4 (OCH3); νmax (KBr...), 68.8 (C2), 65.1 (C3), 54.6 (C5), 53.5 (OCH3) and 22.8 (CH3.../hexane as colourless plates, m.p. 134-142 °C. Found: C, 66.45; H, 6.50; N, 8.00...), 123.9 (ArCH), 96.3 (C4), 66.8 (C5), 64.2 (C2), 53.4 (OCH3), 45...), 67.5 (C2), 64.3 (C3), 52.9 (C5), 45.6 (OCH3), and 23.2 (CH3...), 108.5 (Cq), 90.8 (C4), 64.3 (C5), 63.3 (C2), 53.2 (OCH3), 41...), 64.3 (C2), 63.8 (C3), 53.0 (C5), 46.4 (OCH3), and 22.7 (CH3... CO), 168.5 (ester -OCO), 151.6, 142.2, 140.3, 140.0, 136.5, 129.9 (Cq....8 (Vanillin ArCH), 96.3 (C4), 66.4 (C5), 62.2 (C2), 55.9 (ArOCH3), 52...), 64.3 (C2), 63.8 (C3), 53.0 (C5), 46.4 (OCH3), and 22.7 (CH3...



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0.18/5
...)# l5 I44.93*, I43.75*, 142.49*, I41.71 *, I38.89... F NMR F NMR (CDCh, 188 MHz) c5 -134.23 (ddd, 1 = 6Hz, 12Hz...); 19 F NMR (CDCh, 188 MHz) 6-142.21 (m, 2F), -153.97 (t, 1 = 21... out. 1 H NMR (CDCh, 200 MHz) c5 5.71 (s, IH, CH0 2 ), 3.4-3.9 (m, 4H, OCH2... ); 13 1 C { H} NMR (CDCh, 100 MHz) c5 144.86 (d, 1 =250Hz, CF), 141... 3 ); 19 F NMR (CDC1 3 , 188 MHz) c5- 142.91 (m, 2F), -154.48 (t, 1 = 20... white solid, mp 182 2 3 MHz) c5 168.23, (CO), 82.96... 3 ); 19 F NMR (CDCh, 188 MHz) c5 -141.26 (s, 4F) (see appendix....69 (s, 4F) (see appendix page 142). 2.4.14 5,6,28,29,30,31...-transconfiguration. 1 lljlliljilliptiljlllljlllljlllljlllijlillllll!jlllljlllljlliijiiilJilllllllljllllllllljlltljillljllllllllljlllljl l lljlllljillljlilljlilljlllll -138 ·142 Figure 3.2.8 ·146 19 -150 -154...%; M 470. 1 HNMR (CDCh, 200 MHz) c5 4.15 (t, J =7Hz, 4H, CH20), 2.20...); 13 1 C { H} NMR (CDCI 3 , 62.9 MHz) c5 145.21 (d, J = 245Hz, CF), 140... 2); 19 F NMR (CDCh, 188 MHz) 6 -142.54 (m, 4F, CF ortho to...) o o 19F NMR (CDCh, 188 MHz) o- 142.67 (s, 4F). 3.4.8 2,3,4,5~ Tetrafluoroxylylene~ 1,4~bis(triphenylphosphonium... NMR (DMSO-d6, 300 MHz) c5 8.0-7.6 (ms, 30H, ar. CH), 5.30... C NMR (DMSO-d6, 100 MHz) c5 135.57 (ar. CH), 134...); F NMR (DMSO-d6, 188 MHz) c5 -137.26 (s, 4F) (see appendix.... 96 oc), (CDCh, 200 MHz) c5 3.77 (s, 6H, OCH3 ), 3.73 (s, 6H... shows three new resonances at b -142.11, -156.11 and -162.... 19 F NMR (C 7D 8 , 188 MHz) 6 -142.11, -143.81, -156.11... MHz) c5 7.20 (s, 4H, CH=CH); F NMR (C Ds, 7 8 7 188 MHz) c5 -142.95...]iillllllljlllljlllrjliirjiriljlllrjllll]lllijllii]rirljlllljllll(lllijllllj\llljlllljllrl] -138 -142 -146 -150 -154 -158 I ppm... -135 I I I I I I I I I -145 I I I I I I I I I -155 I I I I I I I I I I I I I I I I -165 pp m 142 5,6,28,29,30,31 ,32...-137-138-139-140.141-142-143-144-145 ppm 151... spectrum TTIIIIII''''I''' 'I' '''I''''I''''I'TTT] 1111111111''''1''''1''''1''''1''''1''''1''''1''''1''''1''''1''''1''''1' ,, '1''''1''''1''''1''''1''''1''''1 -138 -142 -146 -150 -154 -158 pp...



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... h; b Conversion determined by 1H NMR; c5 mol% PPh3 Table 1 - Tertiary Amine... h; b Conversion determined by 1H NMR; c5 mol% PPh3 Table 2 - Secondary Amine....4 MHz, CDCl3, 25 °C): δ = 145.9 (C6), 142.3 (C10), 128.5 (C12), 128.5 (C8... (75.4 MHz, CDCl3, 25 °C): δ = 144.4 (C5), 142.4 (C9), 118 Chapter 7 128.6 (C7....4 MHz, CDCl3, 25 °C): δ = 146.4 (C9), 142.5 (C5), 128.8 (C11), 128.4 (C6 & C7... NMR (75.4 MHz, CDCl3, 25 °C): δ = 142.3 (C5), 140.5 (C9), 128.5 (C7 & C11... C NMR (75.4 MHz, CDCl3, 25 °C): δ = 142.7 (C5), 140.1 (C9), 129.0 (C10), 128... NMR (75.4 MHz, CDCl3, 25 °C): δ = 142.6 (C5), 128.5 (C7), 127.1 (C6), 125....4 MHz, CDCl3, 25 °C): δ = 142.2 (C4), 128.5 (C6), 128.4 (C5), 125.9 (C7), 50... NMR (75.4 MHz, CDCl3, 25 °C): δ = 142.5 (C9), 128.5 (C11), 128.4 (C10..., 25 °C): δ = 152.2 (C11), 142.8 (C4), 141.9 (C8), 128.5 (C5 & C6), 126.0 (C7... (75.4 MHz, CDCl3, 25 °C): δ = 167.9 (C5), 133.3 (C1), 129.9 (C4), 129... C NMR: (CDCl3, 75.4 MHz) δ = 168.8 (C5), 134.2 (C1), 131.7 (C4), 128... °C): δ = 140.9 (C4), 128.4 (C6), 128.2 (C5), 125.9 (C7), 38.2 (C1), 31....4 MHz, DMSO-d6, 25 °C): δ = 145.8 (C5), 128.5 (C7), 126.8 (C6), 126... °C): δ = 143.9 (C4), 128.5 (C6), 127.4 (C5), 126.3 (C7), 47.2 (C3), 37... °C): δ = 157.6 (C7), 132.7 (C4), 129.2 (C5), 113.8 (C6), 55.0 (C8), 38... (75.4 MHz, DMSO-d6, 25 °C): δ = 142.1 (C10), 128.2 (C8), 128.2 (C9... (75.4 MHz, CDCl3, 25 °C): δ = 145.7 (C5), 137.7 (C9), 133.7 (C11), 132...), 137.6 (d, J = 9.3 Hz, C1), 124.5 (d, J = 3.0 Hz, C5), 117.3 (d, J = 7.2 Hz, C4), 116.2 (d, J = 21...) δ = 149.6 (C1), 131.8 (C3), 128.9 (C5), 126.4 (C2), 120.4 (C4), 115...) δ = 148.1 (C1), 138.7 (C3), 128.9 (C5), 116.3 (C4), 112.3 (C2), 108...) δ = 148.8 (C1), 134.9 (C3), 129.9 (C5), 115.1 (C4), 111.4 (C2), 109...), 131.5 (d, J = 31.4 Hz, C3), 129.6 (C5), 124.8 (d, J = 272.1 Hz, C9), 114... consistent with literature data.31 142 Chapter 7 4-(3-Phenylpropyl)morpholine 4.15 According...: (CDCl3, 75.4 MHz) δ = 142.2 (C4), 128.5 (C6), 128.4 (C5), 125.9 (C7), 67...); 13C NMR: (CDCl3, 75.4 MHz) δ = 142.5 (C5), 128.4 (C7), 127.5 (C8), 126...); 13C NMR: (CDCl3, 75.4 MHz) δ = 142.6 (C6), 128.4 (C8), 127.5 (C9...: (CDCl3, 75.4 MHz) δ = 142.5 (C3), 128.4 13 (C5), 127.5 (C6), 126.0 (C4...); C NMR: (CDCl3, 75.4 MHz) δ = 13 142.0 (C5), 128.5 (C7), 127.7 (C8), 126...: (CDCl3, 75.4 MHz) δ = 13 142.3 (C9), 138.2 (C5), 129.2 (C11), 128.5 (C6..., 75.4 MHz) δ = 145.7 (C9), 140.2 (C5), 128.8 (C12), 128.5 (C7), 128...) and isolated as a yellow oil (142 mg, 80%). 1H NMR: (CDCl3...) δ = 167.6 (C1), 135.0 (C2), 131.4 (C5), 128.6 (C4), 127.0 (C3), 40..., 75.4 MHz) δ = 163.1 (d, J = 245.4 Hz, C5), 148.7 (d, J = 6.6 Hz, C3), 130.1 (d, J = 8.1 Hz...: (CDCl3, 75.4 MHz) δ = 143.5 (C6), 142.9 (C5), 139.5 (C3), 118.6 (C8), 117....4 MHz) δ = 162.1 (d, J = 244.7 Hz, C6), 142.4 (d, J = 7.1 Hz, C4), 139.1 (d, J = 3.0 Hz, C3....0 (d, J = 8.4 Hz, C8), 115.8 (d, J = 23.0 Hz, C5), 113.1 (d, J = 20.9 Hz, C7), 65....2 (C4), 143.8 (d, J = 1.1 Hz, C3), 130.0 (C5), 128.8 (d, J = 32.3 Hz, C7), 124..., 75.4 MHz) δ = 161.2 (d, J = 243.6 Hz, C5), 145.8 (d, J = 3.8 Hz, C3), 127.4 (d, J = 15...); 13 C NMR: (CDCl3, 75.4 MHz) δ = 142.6 (C5), 141.0 (C6), 136.6 (C3), 129...) δ = 140.0 (C3), 134.6 (C4), 133.4 (C5), 131.9 (C10), 128.8 (C9), 127...); 13C NMR: (CDCl3, 75.4 MHz) δ = 142.6 (C7), 139.1 (C8), 129.1 (C10...) δ = 170 Chapter 7 143.3 (C3), 136.1 (C5), 136.0 (C8), 129.6 (C7), 128....4 (C8), 140.9 & 140.7 (C3), 135.5 (C5), 128.1 & 128.1 (C4), 126.1 & 125...) δ = 208.2 (C1), 142.1 (C3), 138.0 (C4), 128.8 (C6), 126.9 (C5), 46.7 (C8....4 MHz) δ = 208.4 (C2), 142.4 (C3), 138.1 (C9), 132.2 (C5), 128.7 172 Chapter...) δ = 202.2 (C1), 142.2 (C11), 139.0 (C3), 138.0 (C8), 135.6 (C5), 132.3 (C6....4 (C1), 176 Chapter 7 142.9 (C3), 137.5 (C8), 135.0 (C5), 132.3 (C6), 130...), 138.4 (d, J = 3.1 Hz, C4), 128.2 (d, J = 8.1 Hz, C5), 115.5 (d, J = 21.4 Hz, C6), 115..., C8), 146.9 (C2), 137.8 (d, J = 3.1 Hz, C5), 128.3 (d, J = 8.1 Hz, C7), 115.3 (d, J = 21...), 70.1 (C1), 17.4 (C4), 13.4 (C5); Minor 162.2 (d, J = 244.6 Hz, C9....2 (d, J = 8.1 Hz, C9), 128.1 (C2), 126.8 (C5), 115.6 (d, J = 21.4 Hz, C10), 74....3 (d, J = 245.0 Hz, C8), 139.7 (d, J = 3.1 Hz, C5), 134.3 (C3), 127.6 (d, J = 8.1 Hz, C6..., H7), 139.4 (C2), 138.0 (d, J = 7.8 Hz, C5), 136.3 (d, J = 3.1 Hz, C4), 127.8 (d, J = 8.5 Hz...), 138.1 (d, J = 3.5 Hz, C4), 129.6 (d, J = 5.3 Hz, C5), 125.4 (d, J = 8.1 Hz, C9), 125.1 (d, J = 17....7 (C2), 139.6 (d, J = 3.8 Hz, C4), 128.7 (C5), 126.2 (d, J = 7.2 Hz, C9), 121.1 (d, J = 17...), 116.2 (C3), 115.4 (d, J = 17.8 Hz, C5), 74.3 (d, J = 1.3 Hz, C1); 19F NMR...), 125.2 (qd, J = 4.6 1.7 Hz, C9), 124.5 (C5), 122.7 (q, J = 272.0 Hz, C10), 118...), 129.4 (d, J = 8.3 Hz, C7), 127.8 (d, J = 4.2 Hz, C5), 124.5 (d, J = 3.5 Hz, C6), 115.6 (d, J = 21...) δ = 199.2 (C1), 151.0 (C7), 130.4 (C5), 124.6 (C4), 110.8 (C6), 47...) δ = 199.3 (C1), 154.5 (C7), 130.2 (C5), 126.5 (C4), 113.5 (C6), 48...) δ = 199.1 (C1), 152.3 (C7), 130.6 (C5), 124.5 (C4), 110.2 (C6), 49...) δ = 202.1 (C1), 152.9 (C7), 141.7 (C5), 131.7 (C9), 127.8 (C4), 117....5 (d, J = 3.2 Hz, C8), 116.0 (d, J = 21.9 Hz, C5), 66.9 (C11), 50.3 (d, J = 4.4 Hz, C10....6 (C9), 132.5 (C4), 128.2 (q, J = 5.4 Hz, C5), 125.8 (d, J = 29.6 Hz, C6), 123...



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...-1,3-пентадиена с заданными молекулярными характеристиками» C1-142 C. А. Романов, С. Ю. Ердяков, М. Е. Гурский, Е.С.Гарина, М.Ю. Заремский... и их молекулярных масс турбореометрическим методом» C5-142 Д.А. Маркелов, Ю.Я. Готлиб «Зависимость механических свойств..., C. Plesse, D. Teyssié, C. Chevrot, Synthetic Metals, 142, (2004 )287. 3. F. Vidal, C. Plesse, G. Palaprat... Президиума РАН "Поддержка инноваций и разработок". 142 Секция 2 Устные доклады Акриловые сополимеры..., С5204 Алешин В.В. C3-3 Алиев Л.П. C5-8 Алиев М.А. C5-3, C5-4 Алиновская В.А. C1-197, C2-57..., 276, C4-79, C5-7, C5-81, C5205,C5-207, C5-268 Бакеева И.В. C4-9, C4..., C5-115, C5143 Балабанова Ф.Б. C1-70 Балакин В.М. C1-11, C5187 Балакин К.В. 142 Балакина М.Ю. C3-7, C329, C3-103 Балашов В.А. C1-12, C5-15 Бандурян С.И. C5..., C2-54, C2-55 Бачурин С.О. 142 Баяхметова З.К. C3-77 Беганцова Ю.Е. C3... Бубнов М.П. C1-192 Бубнов Ю.Н. C1-142 Бубнова Л.И. 184 Бугаенко М.Г. 100 Бугаков..., C1177, C4-29, C5-32, C5-33, C5-42, C5-46, C5-166, C5167 Бузинова... Е.В. C5-41 Бурда В.В. C5-27, C5-249 Бурдуковский В.Ф. 108 Бурмистров В.А. C5-22 Бурова Т.В. 254, C5..., C4-79, C5-7, C581, C5-205, C5-207, C5-238, C5-239, C5-268 Вольфсон С.И. C1... О.В. 240 Вялова А.Н. C5-51 Габдрахманов Д.Р. C5-52, C5-53 Габитов И.Т. C1-7, C5-9 Габриелян Г.А. C2... Ганев В. C5-43 Ганина Л.В. C5-56 Ганифаева Н.А. C5-8 Гаппарова Г.И. C1-138, C5-57, C5-58 Гараева Г.Ф. C1-33 Гарина Е.С. C1-76, C1-142, C1-152, C1-195, C5-100 Гарифуллин Д.Ш. C1-11 Гаришин О.К. C5-59..., C5-60 Гегель Н.О. C5-257 Ген Д.Е. 243 Герасименко С.А. C5-61 Герасимов В.И. C5-181, C5-205 Герасимов Р.А. C5-62 Герасин В.А. 190, C1-5, C219, C5-59, C5-63, C5..., C1-76, C1-195, C1-142, C1-143, C1178, C3-17...-96, C1-152, C5-210 Готлиб Ю.Я. 220, C5-74, C5-142 Гофман И.В. 234, C3... В.Я. 254, C5-36, C5-75, C5-84 Гринберг Н.В. 254, C5-36, C5-75, C5-84 Грингольц..., C4-12 Гурский М.Е. C1-142 Гусарова Е.Б. C5-104 Гусев А.В. 244 Гусев К.И. C4..., C2-19, C5-59, C5-63, C5-78 Гуткович С.А. C5-79 Даванков В.А. C5-178 Давиденко... П.В. 246, C580, C5-224 Добровольская И.П. 234, C5-83, C5-191 Добрун Л.А. C5-134 Добрусина... А.В. C4-9 Долгих О.В. C5-158 Долгов В.В. 201 Долгова А.А. C5-7, C5-81 Долгоносова А.М. C5-259 Долгополов...-43 Дубовик А.С. 254, C5-36, C5-75, C5-84 Дубовицкий В.А. C5-48 Дубровский В.В. C4..., C1187, C3-49, C5-107 Ердяков С.Ю. C1-142 Еремина Т.В. C1-51 Ермак... О.Е. C5-231 Запуниди С.А. C3-36 Заремский М.Ю. C1-19, C1-76, C1-142..., C3115, C3-51, C5-118, C5-139, C5-145, C5-151, C5-164, C5200 Иванов...-52 Иванов Р.В. 130, 142, C375 Иванова А.В. C5-97 Иванова В.О. C5-38, C5131 Иванова... Р.С. C1-105 Кожунова Е.Ю. C5-108, C5-169 Козлов А.В. C5-109, C5-231 Козлов В.В. C1...-33, C4-86, C5-133, C5-157, C5-204 Косточко А.В. C5-40, C5135 Костюк...-77, C5-5, C5-205 Курмаз С.В. C1-117, C4-57, C5-101, C5-125, C5-197...-28, C4-29 Лозинский В.И. 130, 142, C2-15, C2-38, C3..., C1177 Макарова Е.Н. C5-56 Макарова Л.И. C5-46, C5166, C5-32 Макарова М.А. C5-47 Маковецкий..., C5-130 Марк С. 105 Маркелов Д.А. C5-142, C5143 Маркин А.В. 209, C5-93, C5-144, C5-208...-163 Масленникова Т.П. C5-83, C5-191 Мастюгин А.В. C5-189 Матвеев В.К. C5-240 Матвеева И.А. C4... Н.Г. C5-38, C5131, C5-132 Матнишян А.А. 270 Матусевич Ю.И. C5-87, C5-263 Матухин Е.Л. C5-40... В.С. 229, 242, 284, C5-155, C5-184, C5-253 Молькин В.Е. C5-186 Монаков Ю.Б. 97... Морозов П.В. C5-156 Москалев И.В. C5-47 Москаленко Ю.Е. C5-150 Москвин Ю.Л. C5-160 Москвина М.А. C5-238..., C4-79, C5-6, C5-109, C5140, C5-160, C5-185, C5208, C5-241 Мукменева Н.А. C3...-67 Никулова У.В. C5-168 Нилов Д.Ю. C5-217 Нистратов А.В. C5-77, C5106, C5-196 Нифантьев...-155, C5-77, C5106, C5-170, C5-171, C5183, C5-192, C5-196 Новакова А.А. C5-169..., C1-177, C5-32, C5-33, C5-36, C5-42, C5-166, C5-248 Паращук Д.Ю. C3... Романов C.А. - C1-142, C1143 Романов Г.А. - C5-44 Ронова И.А. 226, C5-204, C5-219 Рощупкин..., C5-161 Смирнова Л.Г. C5-214 Смирнова Н.М. 136 Смирнова Н.Н. C5-127, C5-144, C5-208, C5-215... Н.П. C4-4 Солдатов В.С. C5-220 Соловова Ю.В. C5-262 Соловская Н.А. C5-223 Соловцова О.В. C5-221 Соловьев... М.В. 177 Тарабукина Е.Б. 228, C5-6, C5-109, C5-231 Тарасевич К. C5-3 Тарасов А.Е. C1-169 Тарасюк...-15 Темнов Д.Э. 247, C5-27, C5-232, C5-243, C5-244 Тепляков В.В. C3-56... Филиппов A.П. 103, 228, 269, C5-6, C5-109, C5-212, C5-231 Филиппов А.Н. C1-178..., C1-13, C2-3, C5-119, C5-120, C5-155, C5-184 Финкельштейн Е.Ш. 106, C1...-14, C5-30, C5-31, C5-66, C5126, C5-168, C5-182, C5193, C5-222 Чапурина..., C5-80, C5-113, C5140, C5-156, C5-191, C5224, C5-235, C5-264 Челушкин П.С. C5-76, C5100, C5-138 Червинский Т.И. C1-193 Червятина М.Е. C5... В. C5-254, C5-255 Шилова И.А. C5-256 Шилова С.В. C3-10 Шинкарев С.М. C5-221 Шипина О.Т. C5... Л.М. 250, 276, C5-7, C5-81, C5-205, C5207, C5-268 Ясина Л.Л. C5-43, C5-138 Ясногородская...